Wherever there is matter in an ever-thinning universe, there might be an entire cosmologically-sized era dominated by an entirely different chemistry to what we have now.

  • thebestaquaman@lemmy.world
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    26 days ago

    Will slowly quantum-tunnel their way to iron.

    While I’m not an astrophysicist, I happen to be a theoretical chemist. While iron is the lowest energy state, you also have to account for entropy here, unless you’re at zero kelvin. Assuming our dead star is in an empty universe without any cosmic microwave background, it will eventually radiate out all heat and (asymptotically) approach zero kelvin, but in finite time you’ll always maintain a number of other elements due to entropy.

    As long as there is background radiation, the star will never get colder than that radiation, and you will maintain some other elements.

      • thebestaquaman@lemmy.world
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        26 days ago

        My background is in materials chemistry, but I’m currently doing research in thermodynamics. Specifically I work on developing predictive models for fluid behaviour. I’ve done some stuff on solids as well, but then mostly on solid-fluid interfaces. Let me know if you want more details :)

        • spittingimage@lemmy.world
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          26 days ago

          More details please.

          I never would have made the connection between chemistry and fluid behaviour. Other than, y’know, this fluid dissolves that.

          • thebestaquaman@lemmy.world
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            26 days ago

            Hehe, I think a lot of people attribute to physics what I attribute to chemistry. Put simply, I (slightly jokingly) say that “chemistry is when there’s too many electrons for the physicists” ;)

            I work in a junction of several fields: One side is in developing equations of state, which means we develop models that tell you everything from how compressible a fluid is, to how much heat it releases when condenses, to what the equilibrium state is (liquid, vapour, several immiscible liquids, etc.), or how the density changes with temperature and pressure, etc. These models primarily apply to bulk fluids at equilibrium. The primary framework we work in here is called “statistical associating fluid theory (SAFT)”.

            Another side is what’s called “interfacial thermodynamics”, which involves looking at how liquid-liquid, liquid-vapour, and fluid-solid interfaces behave. Here we develop models for predicting how surface tension changes under different conditions, the nucleation energy of bubbles and droplets, and how various species “adsorb” on different surfaces/interfaces. The major framework we’re working in here is called “classical density functional theory”, which is quite similar to the more “commonly” known “quantum (or electron) density functional theory”.

            Then there’s irreversible thermodynamics, which is a framework linking local thermodynamic properties (temperature, pressure, chemical potential, etc.) outside equilibrium to transport rates. This lets us model stuff like evaporation rates, ion transfer in batteries, and much more. Essentially, if you have transport processes with more than one driving force (e.g. a battery, where you have simultaneous gradients in temperature, electrical potential, and chemical potential), you need irreversible thermodynamics to make accurate transport models, because Fouriers law, Ficks law, Ohms law, etc. don’t really apply anymore.

            Finally, I’ve done quite a bit of work on transport theory. Specifically, I’ve worked on developing predictive models for the transport properties (viscosity, thermal conductivity, diffusion coefficients, etc.) of fluids at moderate-high pressures. The major framework here is kinetic gas theory, more specifically revised Enskog theory.

            This became quite a list, but yeah… that’s what I do :) let me know if you would like some follow-up reading recommendations or more details:)