Community.

Death note.

Shows like Dark seem an obvious fit for plot > characters. I’d also add The Handmaids Tale here. It should’ve had a stronger plot but had many writing problems. But characters like Serena, Fred (in a horrible way), Lawrence, Lydia were interesting.

And in the reverse, sitcoms mostly are character-driven with just basic templates. Perhaps I should’ve specified what scripted drama shows have better characters than plot.